Researchers create highly conductive metallic gel for 3D printing

Date:
July 5, 2023
Source:
North Carolina State University
Summary:
Researchers have developed a metallic gel that is highly
electrically conductive and can be used to print three-dimensional
(3D) solid objects at room temperature.


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FULL STORY ========================================================================== Researchers have developed a metallic gel that is highly electrically conductive and can be used to print three-dimensional (3D) solid objects
at room temperature.

"3D printing has revolutionized manufacturing, but we're not aware of
previous technologies that allowed you to print 3D metal objects at room temperature in a single step," says Michael Dickey, co-corresponding
author of a paper on the work and the Camille & Henry Dreyfus Professor
of Chemical and Biomolecular Engineering at North Carolina State
University. "This opens the door to manufacturing a wide range of
electronic components and devices." To create the metallic gel, the researchers start with a solution of micron- scale copper particles
suspended in water. The researchers then add a small amount of an indium-gallium alloy that is liquid metal at room temperature. The
resulting mixture is then stirred together.

As the mixture is stirred, the liquid metal and copper particles
essentially stick to each other, forming a metallic gel "network" within
the aqueous solution.

"This gel-like consistency is important, because it means you have a
fairly uniform distribution of copper particles throughout the material," Dickey says.

"This does two things. First, it means the network of particles connect to
form electrical pathways. And second, it means that the copper particles
aren't settling out of solution and clogging the printer." The resulting
gel can be printed using a conventional 3D printing nozzle and retains
its shape when printed. And, when allowed to dry at room temperature,
the resulting 3D object becomes even more solid while retaining its shape.

However, if users decide to apply heat to the printed object while it
is drying, some interesting things can happen.

The researchers found that the alignment of the particles influences how
the material dries. For example, if you printed a cylindrical object,
the sides would contract more than the top and bottom as it dries. If
something is drying at room temperature, the process is sufficiently
slow that it doesn't create structural change in the object. However,
if you apply heat -- for example, put it under a heat lamp at 80 degrees Celsius -- the rapid drying can cause structural deformation. Because
this deformation is predictable, that means you can make a printed object change shape after it is printed by controlling the pattern of the printed object and the amount of heat the object is exposed to while drying.

"Ultimately, this sort of four-dimensional printing -- the traditional
three dimensions, plus time -- is one more tool that can be used to
create structures with the desired dimensions," Dickey says. "But what
we find most exciting about this material is its conductivity.

"Because the printed objects end up being as much as 97.5% metal, they are highly conductive. It's obviously not as conductive as conventional copper wire, but it's impossible to 3D print copper wire at room temperature. And
what we've developed is far more conductive than anything else that can
be printed.

We're pretty excited about the applications here.

"We're open to working with industry partners to explore potential applications, and are always happy to talk with potential collaborators
about future directions for research," Dickey says.

The work was done with support from the National Natural Science
Foundation of China, under grant number 52203101; and from the China Scholarship Council, under grant number 201906250075.

* RELATED_TOPICS
o Matter_&_Energy
# 3-D_Printing # Nature_of_Water # Electronics #
Thermodynamics
o Computers_&_Math
# Virtual_Reality # Computer_Programming # Mathematics
# Math_Puzzles
* RELATED_TERMS
o Gallium o Heavy_metals o Hydrogen o Metal o Cube o
Semiconductor o Friction o Fluid_mechanics

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========================================================================== Related Multimedia:
* Metallic_spider_printed_at_room_temperature_using_the_metallic_gel ========================================================================== Journal Reference:
1. Ruizhe Xing, Jiayi Yang, Dongguang Zhang, Wei Gong, Taylor
V. Neumann,
Meixiang Wang, Renliang Huang, Jie Kong, Wei Qi, Michael D. Dickey.

Metallic gels for conductive 3D and 4D printing. Matter, 2023; 6
(7): 2248 DOI: 10.1016/j.matt.2023.06.015 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2023/07/230705115147.htm

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