Next-generation flow battery design sets records
Sugar additive plays a surprise role, boosting flow battery capacity and longevity for this grid energy resilience design

Date:
July 10, 2023
Source:
DOE/Pacific Northwest National Laboratory
Summary:
A new flow battery design achieves long life and capacity for grid
energy storage from renewable fuels.


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A common food and medicine additive has shown it can boost the capacity
and longevity of a next-generation flow battery design in a record-setting experiment.

A research team from the Department of Energy's Pacific Northwest
National Laboratory reports that the flow battery, a design optimized
for electrical grid energy storage, maintained its capacity to store and release energy for more than a year of continuous charge and discharge.

The study, just published in the journal Joule, details the first use of
a dissolved simple sugar called b-cyclodextrin, a derivative of starch,
to boost battery longevity and capacity. In a series of experiments,
the scientists optimized the ratio of chemicals in the system until it
achieved 60 percent more peak power. Then they cycled the battery over
and over for more than a year, only stopping the experiment when the
plastic tubing failed. During all that time, the flow battery barely
lost any of its activity to recharge. This is the first laboratory-scale
flow battery experiment to report more than a year of continuous use
with minimal loss of capacity.

The b-cyclodextrin additive is also the first to speed the electrochemical reaction that stores and then releases the flow battery energy, in a
process called homogeneous catalysis. This means the sugar does its work
while dissolved in solution, rather than as a solid applied to a surface.

"This is a brand new approach to developing flow battery electrolyte,"
said Wei Wang, a long-time PNNL battery researcher and the principal investigator of the study. "We showed that you can use a totally different
type of catalyst designed to accelerate the energy conversion. And
further, because it is dissolved in the liquid electrolyte it eliminates
the possibility of a solid dislodging and fouling the system." What is a
flow battery? As their name suggests, flow batteries consist of two
chambers, each filled with a different liquid. The batteries charge
through an electrochemical reaction and store energy in chemical
bonds. When connected to an external circuit, they release that energy,
which can power electrical devices. Flow batteries differ from solid-state batteries in that they have two external supply tanks of liquid constantly circulating through them to supply the electrolyte, which is like the
"blood supply" for the system. The larger the electrolyte supply tank,
the more energy the flow battery can store.

If they are scaled up to the size of a football field or more, flow
batteries can serve as backup generators for the electric grid. Flow
batteries are one of the key pillars of a decarbonization strategy to
store energy from renewable energy resources. Their advantage is that
they can be built at any scale, from the lab-bench scale, as in the PNNL
study, to the size of a city block.

Why do we need new kinds of flow batteries? Large-scale energy storage provides a kind of insurance policy against disruption to our electrical
grid. When severe weather or high demand hobble the ability to supply electricity to homes and businesses, energy stored in large-scale flow
battery facilities can help minimize disruption or restore service. The
need for these flow battery facilities is only expected to grow, as
electricity generation increasingly comes from renewable energy sources,
such as wind, solar and hydroelectric power. Intermittent power sources
such as these require a place to store energy until it's needed to meet consumer demand.

While there are many flow battery designs and some commercial
installations, existing commercial facilities rely on mined minerals
such as vanadium that are costly and difficult to obtain. That's why
research teams are seeking effective alternative technologies that use
more common materials that are easily synthesized, stable and non-toxic.

"We cannot always dig the Earth for new materials," said Imre Gyuk,
director of energy storage research at DOE's Office of Electricity. "We
need to develop a sustainable approach with chemicals that we can
synthesize in large amounts - - just like the pharmaceutical and the
food industries." The work on flow batteries is part of a large program
at PNNL to develop and test new technologies for grid-scale energy storage
that will be accelerated with the opening of PNNL's Grid Storage Launchpad
in 2024.

A benign 'sugar water' sweetens the pot for an effective flow battery
The PNNL research team that developed this new battery design includes researchers with backgrounds in organic and chemical synthesis. These
skills came in handy when the team chose to work with materials that
had not been used for battery research, but which are already produced
for other industrial uses.

"We were looking for a simple way to dissolve more fluorenol in our
water-based electrolyte," said Ruozhu Feng, the first author of the
new study. "The b- cyclodextrin helped do that, modestly, but it's
real benefit was this surprising catalytic ability." The researchers
then worked with co-author Sharon Hammes-Schiffer of Yale University,
a leading authority on the chemical reaction underlying the catalytic
boost, to explain how it works.

As described in the research study, the sugar additive accepts
positively charged protons, which helps balance out the movement of
negative electrons as the battery discharges. The details are a bit more complicated, but it's like the sugar sweetens the pot to allow the other chemicals to complete their chemical dance.

The study is the next generation of a PNNL-patented flow battery design
first described in the journal Science in 2021. There, the researchers
showed that another common chemical, called fluorenone, is an effective
flow battery component. But that initial breakthrough needed improvement because the process was slow compared with commercialized flow battery technology. This new advance makes the battery design a candidate for
scale up, the researchers say.

At the same time, the research team is working to further improve
the system by experimenting with other compounds that are similar
to b-cyclodextrin but smaller. Like honey, b-cyclodextrin addition
also makes the liquid thicker, which is less than ideal for a flowing
system. Nonetheless, the researchers found its benefits outweighed
its drawbacks.

Understanding the complex chemistry happening inside the new flow battery design required the expertise of many scientists, including Ying Chen,
Xin Zhang, Peiyuan Gao, Ping Chen, Sebastian Mergelsberg, Lirong Zhong,
Aaron Hollas, Yangang Lian, Vijayakumar Murugesan, Qian Huang, Eric Walter
and Yuyan Shao of PNNL, and Benjamin J. G. Rousseau and Hammes-Schiffer
of Yale, in addition to Feng and Wang.

* RELATED_TOPICS
o Matter_&_Energy
# Batteries # Energy_Technology # Nature_of_Water #
Energy_and_Resources
o Earth_&_Climate
# Energy_and_the_Environment # Renewable_Energy #
Sustainability # Environmental_Science
* RELATED_TERMS
o Renewable_energy o Fuel_cell o Energy_development o
Liquid_nitrogen_economy o Constructal_theory o Wind_power o
Geothermal_power o Alcohol_fuel

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Story Source: Materials provided by
DOE/Pacific_Northwest_National_Laboratory. Original written by Karyn
Hede. Note: Content may be edited for style and length.


========================================================================== Journal Reference:
1. Ruozhu Feng, Ying Chen, Xin Zhang, Benjamin J.G. Rousseau,
Peiyuan Gao,
Ping Chen, Sebastian T. Mergelsberg, Lirong Zhong, Aaron Hollas,
Yangang Liang, Vijayakumar Murugesan, Qian Huang, Eric Walter,
Sharon Hammes- Schiffer, Yuyan Shao, Wei Wang. Proton-regulated
alcohol oxidation for high-capacity ketone-based flow battery
anolyte. Joule, 2023; DOI: 10.1016/j.joule.2023.06.013 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2023/07/230710180520.htm

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